CAS Number 64-19-7, Glacial Acetic Acid USP NF BP Ph Eur Analytical Reagent FCC Food Grade Manufacturers Exporters

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Glacial Acetic Acid Manufacturers Exporters
CAS Number 64-19-7, Glacial Acetic Acid Manufacturer Exporter

For Properties Specifications of Glacial Acetic Acid Click Properties, Specifications of Glacial Acetic Acid Manufacturer.

For Uses of Glacial Acetic Acid Click Uses of Glacial Acetic Acid Manufacturer.

For For SDS MSDS Sheet of Glacial Acetic Acid Click SDS Safety Data Sheet MSDS Sheet of Glacial Acetic Acid Manufacturer.

The Properties and Specifications of Glacial Acetic Acid:

Acetic acid systematically named ethanoic acid is an acidic, colorless liquid and organic compound with the chemical formula CH3COOH. Vinegar is no less than 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water. Acetic acid is an aliphatic organic acid. It is a hygroscopic, corrosive liquid with a vinegar-like odor.

Appearance: Clear water-like liquid.
Melting point: 16C.
Boiling point: 117C to 118C literature.
Relative density: 1.05
pH: around 2.5
FEMA Number: 2006
E number: E260 (Preservative).

Due to melting point of Acetic Acid around 16C, some buyers take acetic acid diluted with water. We can do that job.

Glacial Acetic Acid USP Grade Specifications:
C2H4O2 - 60.05
Acetic acid CAS Number 64-19-7

Glacial Acetic Acid contains NLT 99.5% and NMT 100.5%, by weight, of C2H4O2.

Identification Tests: General, Acetate: Meets the requirements

Sample solution: Measure 2 mL of Glacial Acetic Acid into a glass-stoppered flask, previously tared while containing about 20 mL of water, and weigh again to obtain the weight of the substance under assay.
Analysis: Add 20 mL of water, then add phenolphthalein. Titrate with 1 N sodium hydroxide. Each mL of 1 N sodium hydroxide is equivalent to 60.05 mg of C2H4O2.
Acceptance criteria: 99.5%–100.5%

Limit of Nonvolatile Residue: Evaporate 20 mL in a tared dish, and dry at 105C for 1 h: the weight of the residue does not exceed 1.0 mg.
Chloride and Sulfate, Chloride: To pass the test.
Chloride and Sulfate, Sulfate: To pass the test.
Readily Oxidizable Substances: To pass the test.
Congealing Temperature: NLT 15.6C
Packaging and Storage: Preserve in tight containers, and store at room temperature.

Glacial Acetic Acid BP Ph Eur Grade Specifications:
C2H4O2 - 60.1 - CAS Number 64-19-7

Content: 99.0 per cent m/m to 100.5 per cent m/m.

Appearance: Crystalline mass or clear, colourless, volatile liquid.
Solubility: Miscible with water, with ethanol (96 per cent) and with methylene chloride.

A. A 100 g/L solution is strongly acid.
B. To 0.03 mL add 3& mL of water and neutralise with dilute sodium hydroxide solution. The solution gives reaction (b) of acetates.

Solution S:
Dilute 20 mL to 100 mL with distilled water.
Appearance: The substance to be examined is clear and colourless.
Freezing point: Minimum 14.8C.
Reducing substances: Dilute 2.0 mL to 10.0 mL with water. Add 0.1 mL of 0.02 M& potassium permanganate. Heat on a water-bath for 1 min, the colour remains pink.
Chlorides: Maximum 25 mg/L.
Sulfates: Maximum 50 mg/L, determined on solution S.
Iron: Maximum 5 ppm.
Residue on evaporation: Maximum 0.01 per cent.
Evaporate 20 g to dryness on a water-bath and dry at 100C-105C. The residue weighs a maximum of 2.0 mg.

Specifications of Acetic Acid, Glacial FCC Food Grade
C2H4O2 Formula weight 60.05
INS: 260 CAS 64-19-7
FEMA: 2006

Acetic Acid, Glacial, occurs as a clear, colorless liquid. It boils at about 118°. When well diluted with water (e.g., 1:100), it has a vinegar odor and taste. It is miscible with water, with alcohol, and with glycerin.
Function:Acidifier; flavoring agent.

Identification: A 1:3 aqueous solution gives positive tests for Acetate.
Assay: Not less than 99.5% and not more than 100.5%, by weight, of C2H4O2.
Lead: Not more than 0.5 mg/kg.
Nonvolatile Residue: Not more than 0.005%.
Readily Oxidizable Substances: Passes test.
Solidification Point: Not cooler than 15.6C.

Specifications of Acetic Acid, Glacial Analytical Reagent Grade:
CH3COOH --- Formula Weight 60.05
CAS Number 64-19-7

Assay: 99.7% CH3COOH

Color (APHA): 10
Dilution test: Passes test
Residue after evaporation: 0.001%
Acetic anhydride [(CH3CO)2O]: 0.01%
Chloride (Cl): 1 ppm
Sulfate (SO4): 1 ppm
Heavy metals (as Pb): 0.5 ppm
Iron (Fe): 0.2 ppm
Substances reducing dichromate: Passes test
Substances reducing permanganate: Passes test
Titrable base: 0.0004 meq/g.

The Uses of Glacial Acetic Acid:

Acetic acid is a chemical reagent to produce chemical compounds. The largest single use of acetic acid is in the production of vinyl acetate monomer. The volume of acetic acid used in vinegar is comparatively small. Acetic acid injection into a tumor has been used to treat cancer since the 1800s. Acetic acid is used as part of cervical cancer screening in many areas in the developing world. Vinegar is used directly as a condiment and in the pickling of vegetables and other foods. Acetic acid is a chemical reagent for the production of chemical compounds.

The MSDS-SDS Hazard Statement of Glacial Acetic Acid:

Glacial Acetic Acid SDS, Safety Data Sheet

Section 1 - Chemical Product and Company Identification

Product Name & Other Names: Glacial Acetic Acid or Acetic Acid or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Relevant uses and uses advised against (if any)
: Laboratory and Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Combustible Liquid
Combustible Liquid

GHS Label Elements

Signal Words: Danger

Hazard statements:
H227: Combustible liquid.
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Precautionary statements:
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313: If eye irritation persists: Get medical advice/ attention.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.

Section 3 - Composition/Information on Ingredients

Product Name & Other Names: Glacial Acetic Acid or Acetic Acid or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7

Section 4 - First Aid Measures

Always consult a physician after the first aid is given.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: 40C 104F
Auto Ignition Temperature: 463C or 865F
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Section 6 - Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Remove all ignition sources and ventilate area. Neutralize with sodium bicarbonate or calcium hydroxide or dry soda ash or calcium carbonate and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents, strong alkalis, and metals. Store protected from heat and flames.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA).
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL).
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g., lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Acetic acid.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9 - Physical and Chemical Properties

Appearance: Clear Liquid
Odor: Vinegar odor
Odor threshold: No data found.
pH: 2 for 1% solution, 2.4 (1.0M solution)
Relative density: around 1.05
Boiling Point: 118C (244.5F)
Melting Point:
16.6C (61.9F).
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water
Viscosity: No data found.
Molecular Formula: C2H4O2
Molecular Weight: 60.05

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air, or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis, and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Acute oral toxicity (LD50): 3310 mg/kg [Rat].
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit].
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: No data found.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

Section 12 - Ecological Information

Persistence and Degradability: The material will readily biodegrade.
Mobility: Mobile due to water solubility
Bioaccumulation/ Accumulation: Unlikely to bioaccumulate
Results of PBT and vPvB assessment: No data available for assessment.
(LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia].

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

Section 14 - Transport Information

DOT USA, TDG Canada and ADR/RID Europe
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs.
Marine pollutant: No
Poison Inhalation Hazard: No
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs.
Marine pollutant: No
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial.

Section 15 - Regulatory Information

SARA 311/312 Hazards
: See section 2.
California Prop. 65 Components: Not listed.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H227 = Combustible liquid.
H314 = Causes severe skin burns and eye damage.
H402 = Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C = Corrosive
Risk Phrases:
R10 = Flammable.
R35 = Causes severe burns.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Glacial Acetic Acid Suppliers
Glacial Acetic Acid Structure

CAS Number 64-19-7, Glacial Acetic Acid Manufacturer Exporter

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