CAS Number 7784-24-9 and 10043-67-1, Potassium or Potash Alum or Aluminium Potassium Sulfate USP BP Ph Eur Analytical Reagent FCC Food Grade Manufacturers Exporters
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CAS Number 7784-24-9 and 10043-67-1, Potassium or Potash Alum or Aluminium Potassium Sulfate Manufacturer Exporter
For Properties Specifications of Potassium or Potash Alum or Aluminium Potassium Sulfate Click Properties, Specifications of Potassium or Potash Alum or Aluminium Potassium Sulfate Manufacturer.
For Uses of Potassium or Potash Alum or Aluminium Potassium Sulfate Click Uses of Potassium or Potash Alum or Aluminium Potassium Sulfate Manufacturer.
For For SDS MSDS Sheet of Potassium or Potash Alum or Aluminium Potassium Sulfate Click SDS Safety Data Sheet MSDS Sheet of Potassium or Potash Alum or Aluminium Potassium Sulfate Manufacturer.
The Properties and Specifications of Potassium or Potash Alum or Aluminium Potassium Sulfate:
IUPAC Name: Aluminium potassium sulfate dodecahydrate.
Chemical formula: KAl(SO4)2·12H2O
Molecular weight: 258.19 for anhydrous 474.37 for dodecahydrate.
Melting point: 92C to 95C.
Boiling point: 200C.
Relative density: 1.73
Solubility: Soluble in water.
Potassium Alum USP Grade Specifications:
AIK(SO4)2-12H2O --- 474.39
AIK(SO4)2 --- 258.21
Sulfuric acid, aluminum potassium salt (2:1:1), dodecahydrate;
Aluminum potassium sulfate (1:1:2) dodecahydrate CAS 7784-24-9
Anhydrous CAS 10043-67-1
DEFINITION
Potassium Alum contains NLT 99.0% and NMT 100.5% of potassium alum [AlK(SO4)2], calculated on the dried basis.
IDENTIFICATION
A.
Sample solution: 50 mg/mL in water
Analysis: Add 1 N sodium hydroxide dropwise to the Sample solution.
Acceptance criteria: A precipitate is formed that dissolves in an excess of the reagent. Ammonia is not evolved (distinction from ammonium alum).
B.
Analysis: Hold it in a nonluminous flame.
Acceptance criteria: A violet color is imparted to the flame.
C.
Sample solution: Saturated solution in water
Analysis: Add 10 mL of sodium bitartrate to 5 mL of the Sample solution.
Acceptance criteria: A white, crystalline precipitate is formed within 30 min.
D. Identification Tests—General, Aluminum and Sulfate
Sample solution: Potassium alum in water (1 in 150)
Analysis: Add 5 drops of potassium ferrocyanide TS to 20 mL of the Sample solution.
Acceptance criteria: No blue color is produced immediately.
Loss on Drying:
Sample: 2.0 g
Analysis: Transfer the Sample in a tared porcelain crucible to a muffle furnace at 200C. Increase the temperature to 400C, and dry at 400C to constant weight. Cool in a desiccator, and weigh.
Acceptance criteria: 43.0% to 46.0%
Alum BP Ph Eur Grade Specifications:
Potash Alum BP
Aluminium Potassium Sulphate BP
AlK(SO4)2-12H2O --- 474.4 CAS 7784-24-9
DEFINITION
Content: 99.0 per cent to 100.5 per cent of AlK(SO4)2-12H2O.
CHARACTERS
Appearance: Granular powder or colourless, transparent, crystalline masses.
Solubility: Freely soluble in water, very soluble in boiling water, soluble in glycerol, practically insoluble in ethanol (96 per cent).
IDENTIFICATION
A. Solution S (see Tests) gives the reactions of sulphates.
B. Solution S gives the reaction of aluminium.
C. Shake 10 ml of solution S with 0.5 g of sodium bicarbonate R and filter. The filtrate gives reaction (a) of potassium.
TESTS
Solution S: Dissolve 2.5 g in water R and dilute to 50 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
pH: 3.0 to 3.5.
Ammonium: Maximum 0.2 per cent.
Iron: Maximum 100 ppm.
Heavy metals: Maximum 20 ppm.
Specifications of Aluminum Potassium Sulfate FCC Food Grade:
Aluminum Potassium Sulfate FCC or Potassium Alum FCC
Potassium Alum FCC
AlK(SO4)2-12H2O Formula weight 474.38
INS: 522 CAS: 7784-24-9
DESCRIPTION
Aluminum Potassium Sulfate occurs as large, transparent crystals or crystalline fragments, or as a white crystalline powder. One gram dissolves in 7.5 mL of water at 25C and in about 0.3 mL of boiling water. Its solutions are acid to litmus. It is insoluble in alcohol, but is freely soluble in glycerin.
Function Buffer; neutralizing agent; firming agent.
REQUIREMENTS
Identification: A 1:20 aqueous solution gives positive tests for Aluminum, for Potassium, and for Sulfate.
Assay: Not less than 99.5% and not more than 100.5% of AlK(SO4)2-12H2O.
Ammonium Salts: Passes test.
Fluoride: Not more than 0.003%.
Lead: Not more than 3 mg/kg.
Selenium: Not more than 0.003%.
Specifications of Aluminum Potassium Sulfate Dodecahydrate Analytical Reagent:
Potash Alum
AlK(SO4)2 . 12H2O
Formula Weight 474.39
CAS Number 7784-24-9
REQUIREMENTS
Assay: 98.0-102.0% AlK(SO4)2 .12H2O
MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Chloride (Cl): 5 ppm
Ammonium (NH4): 0.005%
Heavy metals (as Pb): 0.001%
Iron (Fe): 0.001%
Sodium (Na): 0.02%
The Uses of Potassium or Potash Alum or Aluminium Potassium Sulfate:
Potassium or Potash Alum or Aluminium Potassium Sulfate is a fire-retardant. It is used in tanning, pharmaceuticals, water purification, food, dyeing etc. It also has cosmetic uses as a deodorant, as an aftershave treatment and as a styptic for minor bleeding from shaving. It has E Number of E522 acidity regulator.The MSDS-SDS Hazard Statement of Potassium or Potash Alum or Aluminium Potassium Sulfate:
Potassium Alum or Aluminium Potassium Sulphate or Aluminum Potassium Sulfate SDS, Safety Data Sheet
MSDS 13-Mar-22
1. Product Identification
Product Name & Other Names: Potassium Alum or Sulfuric acid, aluminum potassium salt (2:1:1), dodecahydrate or potassium alum dodecahydrate or Alum Potassium Powder or Potash alum or Alum or Kalinite or Aluminium Potassium Sulphate or Aluminum Potassium Sulfate.
CAS No.: 10043-67-1 (Anhydrous) 7784-24-9 (Dodecahydrate)
EINECS EC Number: 233-141-3
Relevant uses and uses advised against (if any) : Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements NONE |
Signal Word: None
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Potassium Alum or Sulfuric acid, aluminum potassium salt (2:1:1), dodecahydrate or potassium alum dodecahydrate or Alum Potassium Powder or Potash alum or Alum or Kalinite or Aluminium Potassium Sulphate or Aluminum Potassium Sulfate
CAS No.: 10043-67-1 (Anhydrous) 7784-24-9 (Dodecahydrate)
EINECS EC Number: 233-141-3
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give copious quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Not considered to be a fire hazard.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Keep in mind that addition of water can cause the formation of sulfuric acid.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At elevated temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover spill with soda ash and mix. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents and metals.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (TWA) total dust and 5 mg/m3 (TWA)
respirable fraction for Aluminum metal as Al.
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 respirable fraction (TWA), Aluminum metal and Insoluble compounds, A4.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Colorless crystals
Odor: Odorless.
Odor threshold: No data found.
pH: 3.3 (0.2 M solution)
Relative density: around 1.73.
Boiling Point: 200C (392F) Loses water
Melting Point: 92.5C (198F)
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: 14% in water, 333% in boiling water
Viscosity: No data found.
Molecular Weight: 474.38
Chemical Formula: AlK(SO4)2 (Anhydrous) or AlK(SO4)2 12H2O (Dodecahydrate).
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Hydrolyzes to form dilute sulfuric acid. Toxic and corrosive oxides of sulfur may be formed when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Corrosive to metals in the presence of water.
Conditions to Avoid: Moisture and incompatibles.
11. Toxicological Information
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.
Mutagenic Effects: No data found.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.
12. Ecological Information
Environmental Toxicity: No data found.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA/ICAO: Not regulated.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
Disclaimer:********************************
Our company provides this SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Potassium or Potash Alum or Aluminium Potassium Sulfate
Structure
CAS Number 7784-24-9 and 10043-67-1, Potassium or Potash Alum or Aluminium Potassium Sulfate Manufacturer Exporter
ANMOL CHEMICALS & PHARMACEUTICALS Pvt. Ltd.
India, USA, Europe, UAE
TELEPHONE: +912223770100
Navi Mumbai, INDIA
e-mail: info(At the rate i.e. @)anmol.org
Copyright. 9-nov-24
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