CAS Number 65-85-0, Benzoic Acid USP BP Ph Eur IP Analytical Reagent FCC Food Grade Manufacturers Exporters
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CAS Number 65-85-0, Benzoic Acid Manufacturer Exporter
For Properties Specifications of Benzoic Acid Click Properties, Specifications of Benzoic Acid Manufacturer.
For Uses of Benzoic Acid Click Uses of Benzoic Acid Manufacturer.
For For SDS MSDS Sheet of Benzoic Acid Click SDS Safety Data Sheet MSDS Sheet of Benzoic Acid Manufacturer.
The Properties and Specifications of Benzoic Acid:
Benzoic Acid USP Grade Specifications
C7H6O2 --- 122.12
Benzoic acid CAS 65-85-0
Benzoic Acid contains not less than 99.5 percent and not more than 100.5 percent of C7H6O2, calculated on the anhydrous basis.
Identification: Prepare a saturated solution of Benzoic Acid in water, and filter twice. To one portion of the filtrate add ferric chloride TS: a salmon-colored precipitate is formed. To a separate 10-mL portion of the filtrate add 1 mL of 7 N sulfuric acid and cool the mixture: a white precipitate forms in about 10 minutes; this precipitate is soluble in ether.
Congealing range: between 121 and 123.
Water: not more than 0.7%, a 1 in 2 solution of methanol in pyridine being used as the solvent.
Readily carbonizable substances: Dissolve 500 mg in 5 mL of sulfuric acid TS: the solution has no more color than Matching Fluid Q.
Residue on ignition: not more than 0.05%.
Heavy metals: Dissolve 2.0 g in 25 mL of acetone, and add 2 mL of water. Add 1.2 mL of thioacetamide-glycerin base TS and 2 mL of pH 3.5 Acetate Buffer, and allow to stand for 5 minutes: any color produced is not darker than that of a control made with 25 mL of acetone, 2.0 mL of Standard Lead Solution, and treated in the same manner. The limit is 10µg per g.
Readily oxidizable substances: Add 1.5 mL of sulfuric acid to 100 mL of water, heat to boiling, and add 0.1 N potassium permanganate, drop wise, until the pink color persists for 30 seconds. Dissolve 1.00 g of Benzoic Acid in the hot solution, and titrate with 0.1 N potassium permanganate VS to a pink color that persists for 15 seconds: not more than 0.50 mL of 0.10 N potassium permanganate is consumed.
Benzoic Acid BP Ph Eur Grade Specifications
C7H6O2 -- 122.1 -- CAS 65-85-0
DEFINITION
Benzoic acid contains not less than 99.0 per cent and not more than the equivalent of 100.5 per cent of benzene carboxylic acid.
CHARACTERS
A white, crystalline powder or colourless crystals, odourless or with a very slight characteristic odour, slightly soluble in water, soluble in boiling water, freely soluble in alcohol and in fatty oils.
IDENTIFICATION
A. Melting point 121C to 124C.
B. Solution S (see Tests) gives reaction (a) of benzoates.
TESTS
Solution S: Dissolve 5.0 g in alcohol and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
Carbonizable substances: Dissolve 0.5 g with shaking in 5 ml of sulphuric acid. After 5 min, the solution is not more intensely coloured than reference solution.
Oxidizable substances: Dissolve 0.2 g in 10 ml of boiling water. Cool, shake and filter. To the filtrate add 1 ml of dilute sulphuric acid and 0.2 ml of 0.02 M potassium permanganate. After 5 min, the solution is still coloured pink.
Halogenated compounds and halides: All glassware used must be chloride-free and may be prepared by soaking overnight in a 500 g/l solution of nitric acid, rinsed with water and stored full of water. It is recommended that glassware be reserved for this test.
Solution (a) Dissolve 6.7 g of the substance to be examined in a mixture of 40 ml of 1 M sodium hydroxide and 50 ml of alcohol and dilute to 100.0 ml with water. To 10.0 ml of this solution add 7.5 ml of dilute sodium hydroxide solution and 0.125 g of nickel-aluminium alloy and heat on a water-bath for 10 min. Allow to cool to room temperature, filter into a 25 ml volumetric flask and wash with three quantities, each of 2 ml, of alcohol. Dilute the filtrate and washings to 25.0 ml with water. This solution is used to prepare solution A.
Solution (b) In the same manner, prepare a similar solution without the substance to be examined. This solution is used to prepare solution B.
In four 25 ml volumetric flasks, place separately 10 ml of solution (a), 10 ml of solution (b), 10 ml of chloride standard solution (8 ppm Cl) (used to prepare solution C) and 10 ml of water. To each flask add 5 ml of ferric ammonium sulphate solution, mix and add drop wise and with swirling 2 ml of nitric acid and 5 ml of mercuric thiocyanate solution. Shake. Dilute the contents of each flask to 25.0 ml with water and allow the solutions to stand in a water-bath at 20C for 15 min. Measure at 460 nm the absorbance of solution A using solution B as the compensation liquid, and the absorbance of solution C using the solution obtained with 10 ml of water as the compensation liquid. The absorbance of solution A is not greater than that of solution C (300 ppm).
Heavy metals: 12 ml of solution S complies with limit test B for heavy metals (10 ppm).
Sulphated ash: Not more than 0.1 per cent, determined on 1.0 g.
Benzoic Acid FCC Food Grade Specifications
C7H6O2 Formula weight 122.12
INS: 210 CAS 65-85-0
DESCRIPTION
Benzoic Acid occurs as white crystals, scales, or needles. It begins to sublime at about 100C and is volatile with steam. One gram is soluble in 275 mL of water at 25C, in 20 mL of boiling water, in 3 mL of alcohol, in 5 mL of chloroform, and in 3 mL of ether. It is soluble in fixed and in volatile oils and is sparingly soluble in hexane.
REQUIREMENTS
Identification: Dissolve 1 g of sample in a 20:1 (v/v) mixture of water and 1 N sodium hydroxide, filter the solution, and add about 1 mL of ferric chloride TS. A buff-colored precipitate forms.
Assay: Not less than 99.5% and not more than 100.5% of C7H6O2, calculated on the anhydrous basis.
Lead: Not more than 2.0 mg/kg.
Readily Carbonizable Substances: Passes test.
Readily Oxidizable Substances: Passes test.
Residue on Ignition: Not more than 0.05%.
Solidification Point: Between 121-123C.
Water: Not more than 0.7%.
Benzoic Acid Analytical Reagent Grade Specifications
C6H5COOH
Formula Weight 122.12
CAS Number 65-85-0
REQUIREMENTS
Assay: 99.5% C6H5COOH
Freezing point: 122-123C
MAXIMUM ALLOWABLE
Residue after ignition: 0.005%
Insoluble in methanol: 0.005%
Chlorine compounds (as Cl): 0.005%
Sulfur compounds (as S): 0.002%
Heavy metals (as Pb): 5 ppm
Substances reducing permanganate: Passes test
Benzoic Acid IP Grade is also supplied.
The Uses of Benzoic Acid:
Benzoic acid is used to produce a wide range of products such as perfumes, dyes, topical drugs and insect repellents. The salt of benzoic acid is widely used as a food pH adjuster and preservative, stopping microbes from developing to keep food healthy.
The MSDS-SDS Hazard Statement of Benzoic Acid:
Benzoic Acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 04-Jan-23
1. Product Identification
Product Name & Other Names: Benzoic Acid or Benzenecarboxylic acid or benzeneformic acid or phenyl carboxylic acid or phenyl formic acid or dracylic acid.
CAS No.: 65-85-0
EINECS EC Number: 200-618-2
Molecular Weight: 122.12
Chemical Formula: C6H5COOH
Relevant uses and uses advised against (if any): Industrial Manufacturing.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin corrosion/irritation (Category 2) H315
Eye damage (Category 1), H318
Specific target organ toxicity, repeated exposure (Category 1) H372
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Corrosive |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H315 Causes skin irritation.
H318 Causes serious eye damage.
H372 Causes damage to organs (Lungs) through prolonged or repeated exposure if inhaled.
Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P314 Get Medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Benzoic Acid or Benzenecarboxylic acid or benzeneformic acid or phenyl carboxylic acid or phenyl formic acid or dracylic acid.
CAS No.: 65-85-0
EINECS EC Number: 200-618-2
4. First Aid Measures
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Flash point: 121C (250F) CC
Auto ignition temperature: 570C (1058F)
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Minimum exposable concentration 0.011 g/l. Vapor may explode if ignited in an enclosed area. Vapor from molten benzoic acid may form explosive mixture with air.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Neutralize the residue with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and allow to drain as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and metals. Keep in a well closed container stored under cold to warm conditions, 2 to 40 C, (36 to 104F). Isolate from any source of heat or ignition. Isolate from oxidizing materials. Isolate from flammable materials.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: White, needle-like crystals.
Odor: Faint pleasant odor.
Odor threshold: Not available.
pH: 2.8 (saturated solution @ 25 0C)
Relative density: around 1.32
Boiling Point: 249C (480F)
Melting Point: 122C (252F)
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Density (Air=1): 4.2
Vapor Pressure (mm Hg): 1 @ 96C (205F)
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 0.29 g / 100 ml. water; sinks in water.
Viscosity: Not available.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Emits toxic vapors and gas including phenol, benzene, and carbon monoxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, bases, and metals. Water solutions can react with metals to produce hydrogen gas.
Conditions to Avoid: Heat, flame, ignition sources, dusting, and incompatibles.
11. Toxicological Information
Oral rat LD50: 1700 mg/kg; LC50 rat > 26,000mg/L/Hr.; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 100 mg severe; investigated as a mutagen.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. Ecological Information
Environmental Fate: When released into the soil, Benzoic Acid may leach into groundwater. When released into the soil, Benzoic Acid is expected to readily biodegrade. When released into water, Benzoic Acid is expected to readily biodegrade. This material may bio accumulation to some extent. When released into the air, this material is expected to be moderately removed from the atmosphere by wet deposition.
Environmental Toxicity: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO: Not controlled.
IATA/ICAO: Not controlled.
15. Regulatory Information
SARA 311/312: Immediate Health Hazard. See section 2.
16. Other Information
Disclaimer:
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Our company provides this Benzoic Acid SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Benzoic Acid MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Benzoic Acid Structure
CAS Number 65-85-0, Benzoic Acid Manufacturer Exporter
ANMOL CHEMICALS & PHARMACEUTICALS Pvt. Ltd.
India, USA, Europe, UAE
TELEPHONE: +912223770100
Navi Mumbai, INDIA
e-mail: info(At the rate i.e. @)anmol.org
Copyright. 11-dec-24
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