CAS Number 548-62-9, Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet USP BP Ph Eur Grade Manufacturers Exporters
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CAS Number 548-62-9, Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Manufacturer Exporter
For Properties Specifications of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Click Properties, Specifications of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Manufacturer.
For Uses of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Click Uses of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Manufacturer.
For For SDS MSDS Sheet of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Click SDS Safety Data Sheet MSDS Sheet of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Manufacturer.
The Properties and Specifications of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet:
Gentian Violet USP Grade Specifications , Crystal Violet
Gentian Violet USP
C25H30ClN3 407.98
Methanaminium, N-[4-[bis[4-(dimethylamino)phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-Nmethyl-,chloride.
C. I. Basic violet 3.
[4-[Bis[p-(dimethylamino)phenyl]methylene]-2,5-cyclohexadien-1-ylidene]dimethylammonium chloride [CAS 548-62-9].
Gentian Violet contains not less than 96.0 percent and not more than 100.5 percent of gentian violet (C25H30ClN3), calculated on the anhydrous basis.
Identification—
A: Sprinkle about 1 mg on 1 mL of sulfuric acid: it dissolves in the acid with an orange or brown red color. When this solution is diluted cautiously with water, the color changes to brown, then to green, and finally to blue.
B: Dissolve about 20 mg in 10 mL of water, and add 5 drops of hydrochloric acid. To 5 mL of this solution add tannic acid TS drop wise: a deep blue precipitate is formed.
C: To the remainder of the solution prepared for Identification test B add about 500 mg of zinc dust, and warm the mixture: rapid de-colorization occurs. Place a drop of the decolorized solution adjacent to a drop of 6 N ammonium hydroxide on a filter paper: a blue color is produced at the zone of contact.
Water: not more than 7.5%.
Residue on ignition: not more than 1.5%.
Alcohol-insoluble substances— Boil 1.0 g, accurately weighed, with 50 mL of alcohol under a reflux condenser for 15 minutes, filter through a tarred filtering crucible, wash the residue on the filter with hot alcohol until the last washing is not colored violet, and dry the crucible at 105 for 1 hour: not more than 1.0% of insoluble residue remains.
Arsenic— The limit is 0.001%.
Lead—The limit is 0.003%.
Zinc—
Zinc standard stock solution— Transfer about 1 g of zinc, accurately weighed, to a 1000-mL volumetric flask, add 50 mL of nitric acid, and mix to dissolve. Dilute with water to volume, and mix.
Standard preparation— Dilute the Zinc standard stock solution with water to obtain a Standard preparation containing 0.50 Ag of zinc per mL.
Test preparation— Weigh accurately 0.50 g of Gentian Violet in a suitable tarred crucible. Place in a low-temperature plasma ashing apparatus, and ash until a constant weight is attained. Pipette 10 mL of 6 N nitric acid into the crucible, and heat to dissolve the ash. Transfer the solution to a 500-mL volumetric flask, dilute with water to volume, and mix. Prepare a reagent blank.
Procedure— Concomitantly determine the absorbance of the Standard preparation, the Test preparation, and the reagent blank at the zinc emission line at 213.9 nm, with a suitable atomic absorption spectrophotometer (see Spectrophotometry and Light-Scattering 851) equipped with a zinc lamp and an air–acetylene flame, using water as the blank. The absorbance of the Test preparation, corrected for that of the reagent blank, is not greater than the absorbance of the Standard preparation, similarly corrected (0.05%).
Specifications of Methylrosanilinium Chloride BP Ph Eur Grade:
C25H30ClN3 --- 408.0 --- CAS 548-62-9
Action and use: Antiseptic dye (gentian violet).
DEFINITION
N-[4-[Bis[4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dienylidene]-N-methylmethanaminium chloride (hexamethyl-p-rosanilinium chloride). It contains not more than 10 per cent of pentamethyl-p-rosanilinium chloride and is also known as crystal violet and gentian violet.
Content: 95.0 per cent to 103.0 per cent (anhydrous substance).
CHARACTERS
Appearance: Dark green, shiny powder, hygroscopic.
Solubility: Sparingly soluble in water, freely soluble in ethanol (96 per cent) and in methylene chloride..
IDENTIFICATION
First identification: A.
Second identification: B, C
A. Infrared absorption spectrophotometry.
B. Thin-layer chromatography. To pass the test.
C. Dissolve 50 mg in water and dilute to 5 mL with the same solvent; add 3 mL of dilute sulfuric acid, 1g of zinc powder and heat gently. The mixture decolourises. Filter. To 3 mL of the filtrate add 0.5 mL of silver nitrate solution. A white turbidity is produced which slowly forms a dark, coagulating precipitate.
N,N-Dimethylaniline: Maximum 100 ppm. To pass the test.
Pentamethyl-p-rosanilinium: pentamethyl-p-rosanilinium: maximum 10 per cent. To pass the test
Related substances: To pass the test.
Water: Maximum 10.0 per cent, determined on 0.100 g.
Sulfated ash: Maximum 1.5 per cent, determined on 1.0 g.
The Uses of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet:
Gentian violet belongs to the group of medicines called antifungals. Topical gentian violet is used to treat some types of fungus infections inside the mouth (thrush) and of the skin. Historically used as an anti-bacterial and anti-fungal medecine. It is commonly used for the diagnosis or treatment of minor cuts and scrapes , fungal infections of the skin, athlete's foot.
The MSDS-SDS Hazard Statement of Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet:
Gentian Violet SDS Crystal Violet Methylrosanilinium Chloride
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 11-Jan-23
1. Product Identification
Product Name & Other Names: Gentian Violet or Methylrosanilinium Chloride or Crystal violet or CI Basic Violet 3.
CAS No.: 548-62-9
EINECS EC Number: 208-953-6
Molecular Weight: 407.99
Chemical Formula: C25H30ClN3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral Category 4, H302
Serious eye damage Category 1, H318
Carcinogenicity Category 2, H351, H410
Hazardous to the aquatic environment, long-term hazard Category 1
Labeling according Regulation (EC) No 1272/2008
GHS Label Elements  Health Hazard |
GHS Label Elements |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Gentian Violet or Methylrosanilinium Chloride or Crystal violet or CI Basic Violet 3.
CAS No.: 548-62-9
EINECS EC Number: 208-953-6
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Allow the victim to rest in a well-ventilated area. Seek immediate medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes and wash before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention immediately.
5. Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizers. Store away from sources of heat, moisture.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: Gentian Violet is dark green powder or greenish glistening pieces having a metallic luster.
Odor: Gentian Violet has slight characteristic odor.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: 215C (419F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition it emits toxic fumes of nitrogen oxides and hydrogen chloride.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
Acute toxicity:
LD50 Oral - Mouse - 96 mg/kg.
LD50 Oral - Rabbit - 150 mg/kg.
LD50 Intraperitoneal - Rat - 8,9 mg/kg.
LD50 Intraperitoneal - Mouse - 5,1 mg/kg.
LD50 Intraperitoneal - Rabbit - 5 mg/kg.
LD50 Intraduodenal - Rabbit - 160 mg/kg.
Investigated as a tumorigen, mutagen, reproductive effector.
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
12. Ecological Information
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,35 mg/l - 48 h
Toxicity to algae: EC50 - Pseudokirchneriella subcapitata - 0,42 mg/l - 72 h
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III.
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III.
IATA/ICAO:
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III.
15. Regulatory Information
USA:
SARA 311/312 Hazard Categories: See section 2.
California Proposition 65: Not listed.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Structure
CAS Number 548-62-9, Crystal Violet, Basic Violet #3 Methylrosanilinium Chloride, Gentian Violet Manufacturer Exporter
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India, USA, Europe, UAE
TELEPHONE: +912223770100
Navi Mumbai, INDIA
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Copyright. 1-feb-23
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