CAS Number 471-34-1, Calcium Carbonate USP BP Ph Eur Analytical Reagent FCC Food Grade Manufacturers Exporters
CAS Number 471-34-1, Calcium Carbonate Manufacturer ExporterFor Properties Specifications of Calcium Carbonate Click Properties, Specifications of Calcium Carbonate Manufacturer.
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The Properties and Specifications of Calcium Carbonate:
Calcium Carbonate USP
CaCO3 100.09
Carbonic acid, calcium salt (1:1)Calcium Carbonate, dried at 200 for 4 hours, contains calcium equivalent to not less than 98.0 percent and not more than 100.5 percent of CaCO3.
Identification: The addition of acetic acid to it produces effervescence (presence of carbonate), and the resulting solution, after boiling, responds to the tests for Calcium.
Loss on drying: Dry it at 200 for 4 hours: it loses not more than 2.0% of its weight.
Acid-insoluble substances: Mix 5.0 g with 10 mL of water, and add hydrochloric acid, drop wise, with agitation, until it ceases to cause effervescence, then add water to make the mixture measure 200 mL, and filter. Wash the insoluble residue with water until the last washing shows no chloride, and ignite: the weight of the residue does not exceed 10 mg (0.2%).
Limit of fluoride: The limit is 0.005%.
Arsenic— The limit is 3 ppm.
Barium: A platinum wire, dipped in the filtrate obtained in the test for Acid-insoluble substances and held in a non-luminous flame, does not impart a green color.
Lead : the limit is 3 ppm.
Iron: To pass the test
Mercury: the limit is 0.5 µg per g.
Limit of magnesium and alkali salts: Mix 1.0 g with 35 mL of water, carefully add 3 mL of hydrochloric acid, heat the solution, and boil for 1 minute. Rapidly add 40 mL of oxalic acid TS, and stir vigorously until precipitation is well established. Add immediately to the warm mixture 2 drops of methyl red TS and then 6 N ammonium hydroxide, drop wise, until the mixture is just alkaline. Cool to room temperature, transfer to a 100-mL graduated cylinder, dilute with water to 100 mL, mix, and allow to stand for 4 hours or overnight. Filter, and to 50 mL of the clear filtrate in a platinum dish add 0.5 mL of sulfuric acid, and evaporate the mixture on a steam bath to a small volume. Carefully heat over a free flame to dryness, and continue heating to complete decomposition and volatilization of ammonium salts. Finally ignite the residue to constant weight.
The weight of the residue does not exceed 5 mg (1.0%).
Heavy metals: the limit is 0.002%.
Organic volatile impurities: meets the requirements.
Calcium Carbonate BP Specifications
CaCO3 -- 100
Action and use: Antacid.DEFINITION
Content: 98.5 per cent to 100.5 per cent (dried substance).CHARACTERS
Appearance: White or almost white powder.
Solubility: Practically insoluble in water.IDENTIFICATION
A. It gives the reaction of carbonates
B. 0.2 ml of solution S (see Tests) gives the reactions of calciumTESTS
Solution S: Dissolve 5.0 g in 80 ml of dilute acetic acid R . When the effervescence ceases, boil for 2min. Allow to cool, dilute to 100 ml with dilute acetic acid R and filter, if necessary, through a sintered-glass filter.
Substances insoluble in acetic acid: Maximum 0.2 per cent.
Chlorides: Maximum 330 ppm.
Sulphates: Maximum 0.25 per cent.
Arsenic: Maximum 4 ppm, determined on 5 ml of solution S.
Barium: To 10 ml of solution S add 10 ml of calcium sulphate solution R . After at least 15 min, any opalescence in the solution is not more intense than that in a mixture of 10 ml of solution S and 10 ml of distilled water R.
Iron: Maximum 200 ppm.
Magnesium and alkali metals: Maximum 1.5 per cent.
Heavy metals: Maximum 20 ppm.
Calcium Carbonate FCC Food Grade as per US Food Chemical Codex
CaCO3 Formula weight 100.09
CAS: 471-34-1DESCRIPTION
Calcium Carbonate occurs as a fine, white or colorless, microcrystalline powder. It is stable in air, and it is practically insoluble in water and in alcohol. The presence of any ammonium salt or carbon dioxide increases its solubility in water, but the presence of any alkali hydroxide reduces the solubility.
Function: pH control agent; nutrient; dough conditioner; firming agent; yeast nutrient.REQUIREMENTS
Identification: A sample dissolves, with effervescence, in 1 N acetic acid, in 2.7 N hydrochloric acid, and in 1.7 N nitric acid, and the resulting solutions, after boiling, give positive tests for Calcium.
Assay: Not less than 98.0% and not more than 100.5% of CaCO3 after drying.
Acid-Insoluble Substances: Not more than 0.2%.
Arsenic: Not more than 3 mg/kg.
Fluoride: Not more than 0.005%.
Lead: Not more than 3 mg/kg.
Loss on Drying: Not more than 2%.
Magnesium and Alkali Salts: Not more than 1%.
Calcium Carbonate Analytical Reagent Specifications
REQUIREMENTS
CaCO3
Formula Weight 100.09
CAS Number 471-34-1
Assay (dried basis) 99.0% CaCO3 min
MAXIMUM ALLOWABLE
Insoluble in dilute hydrochloric acid 0.01% Ammonium hydroxide precipitate 0.01% Chloride (Cl) 0.001% Sulfate (SO4) 0.0015% Ammonium (NH4) 0.003% Barium (Ba) 0.01% Heavy metals (as Pb) 0.001% Iron (Fe) 0.003% Magnesium (Mg) 0.02% Potassium (K) 0.01% Sodium (Na) 0.1% Strontium (Sr) 0.1% Calcium Carbonate IP Grade is also supplied.
The Uses of Calcium Carbonate:
Calcium carbonate is a dietary supplement used when the amount of calcium taken in the diet is not enough. Calcium is needed by the body for healthy bones, muscles, nervous system, and heart. Calcium carbonate also is used as an antacid to relieve heartburn, acid indigestion, and upset stomach. In the food industry, calcium carbonate is known as additive E170. It is used in pastries, chewing gums, some breadstuffs, crisps and cookies. It is widely used as a pharmaceutical excipient.
The MSDS-SDS Hazard Statement of Calcium Carbonate:
Calcium Carbonate (Calcite or Limestone) SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 06-Jan-231. Product Identification
Product Name & Other Names: Calcium Carbonate; Carbonic acid calcium salt; calcite; aragonite; limestone.
CAS No.: 471-34-1 or 1317-65-3
EINECS EC Number: 207-439-9 or 215-279-6
Molecular Weight: 100.09
Chemical Formula: CaCO3
Relevant uses and uses advised against (if any): Laboratory Chemicals and Industrial Manufacturing Use.2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
NONESignal Word: None
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.3. Composition/Information on Ingredients
Product Name & Other Names: Calcium Carbonate; Carbonic acid calcium salt; calcite; aragonite; limestone.
CAS No.: 471-34-1 or 1317-65-3
EINECS EC Number: 207-439-9 or 215-279-64. First Aid Measures
Always seek medical advice after the first aid treatment.
Skin: Wash exposed area with soap and water.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.5. Fire Fighting Measures
Fire: Calcium Carbonate is not considered to be a fire hazard.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Vacuum or sweep up and remove to an approved disposal container.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, fluorine, magnesium with hydrogen.8. Exposure Controls/Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.
Exposure Limits:
TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total.
TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.
TWA: 10 (mg/m3) from ACGIH (TLV) [United States]
TWA: 10 (mg/m3) [United Kingdom (UK)] Inhalation Total.
TWA: 4 (mg/m3) [United Kingdom (UK)] Inhalation Respirable.3
Consult local authorities for acceptable exposure limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.9. Physical and Chemical Properties
Appearance: Calcium Carbonate is fine, white powder.
Odor: Odorless.
Odor threshold: Not available.
pH: >7.
Relative density: 2.7 - 2.95
Melting Point: 825C (1517F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 0.001 gm in 100 ml water, soluble in dilute acids.
Viscosity: Not available.10. Stability and Reactivity
Stability: Calcium Carbonate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition (825C), emits calcium oxide fumes and liberates carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, fluorine, magnesium with hydrogen.
Conditions to Avoid: Heat, incompatibles.11. Toxicological Information
Acute toxicity: LD50 Oral - Rat - 6,450 mg/kg(Calcium carbonate)
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
Although pure Calcium Carbonate is quite safe in handling, impurities in it can be damaging.12. Ecological Information
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO: Not controlled.
IATA/ICAO: Not controlled.15. Regulatory Information
USA Regulations:
16. Other Information
SARA 311/312 Hazardous Categorization: Not applicable.
California Proposition 65: This product does not contain any Proposition 65 chemicalsDISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Anmol Chemicals & Pharmaceuticals Pvt. Ltd. is an off-shoot of Anmol Chemicals Taloja. It is located in MIDC Taloja and it is manufacturing pharmaceutical grades of API, Excepients, Food grade and Reagent grade chemicals. Anmol Chemicals & Pharmaceuticals Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies for actual users, retail or small pack supplies for research and development chemicals, fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, Analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals, Mineral Fortifiers at best prices.
Calcium Carbonate StructureCAS Number 471-34-1, Calcium Carbonate Manufacturer Exporter
ANMOL CHEMICALS & PHARMACEUTICALS Pvt. Ltd.
India, USA, Europe, UAE
TELEPHONE: +912223770100
Navi Mumbai, INDIAe-mail: info(At the rate i.e. @)anmol.org
Copyright. 8-jan-23
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