CAS Number Monohydrate 10034-96-5 and Anhydrous 7785-87-7, Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous USP BP Ph Eur Analytical Reagent FCC Food Grade Manufacturers Exporters
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CAS Number Monohydrate 10034-96-5 and Anhydrous 7785-87-7, Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Manufacturer Exporter
For Properties Specifications of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Click Properties, Specifications of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Manufacturer.
For Uses of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Click Uses of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Manufacturer.
For For SDS MSDS Sheet of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Click SDS Safety Data Sheet MSDS Sheet of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Manufacturer.
The Properties and Specifications of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous:
Manganese Sulphate Monohydrate BP Ph Eur Grade Specifications|
MnSO4-H2O
DEFINITION
Content: 99.0 per cent to 101.0 per cent (ignited substance).
CHARACTERS
Appearance: Pale pink crystalline powder, slightly hygroscopic.
Solubility: Freely soluble in water, practically insoluble in ethanol (96 per cent).
IDENTIFICATION
A. Solution S (see Tests) gives reaction of sulphates.
B. Dissolve 50 mg in 5 ml of water. Add 0.5 ml of ammonium sulphide solution. A pale pink precipitate is formed which dissolves on the addition of 1 ml of anhydrous acetic acid.
C. Loss on ignition (see Tests).
TESTS
Solution S: Dissolve 10.0 g in distilled water and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is not more opalescent than reference suspension.
Chlorides: Maximum 100 ppm.
Iron: Maximum 10 ppm, determined on solution S.
Zinc: Maximum 50 ppm.
Heavy metals: Maximum 20 ppm.
Loss on ignition: 10.0 per cent to 12.0 per cent, determined on 1.00 g at 500 ± 50C.
Manganese Sulphate BP Ph Eur Grade Specifications
MnSO4-4H2O
DEFINITION
Manganese Sulphate is manganese (II) sulphate tetrahydrate. It contains not less than 98.0% and not more than 100.5% of MnSO4, calculated with reference to the substance ignited at 450 to 500C.
CHARACTERISTICS
Pale pink crystals or crystalline powder.
Freely soluble in water; practically insoluble in ethanol (96%).
IDENTIFICATION
A. Dissolve 0.5 g in 10 ml of water and add 1 ml of sodium sulphide solution. A pink precipitate is produced which is soluble in 6M acetic acid.
B. To 0.1 g add 2 g of lead-(IV) oxide and 5 ml of nitric acid , boil gently for a few minutes, add 100 ml of water and filter. A purple solution is produced.
C. Yields the reactions characteristic of sulphates.
TESTS
Arsenic: 4 ppm
Heavy metals: 40 ppm
Iron: 40 ppm
Zinc: 500 ppm
Chloride: 330 ppm
Loss on ignition: When ignited to constant weight at 450° to 500°, loses 31.0 to 34.0% of its weight. Use 1 g.
Manganese Sulfate USP Grade Specifications
MnSO4-H2O -- 169.02
Sulfuric acid, manganese(2+) salt (1:1) monohydrate.
Manganese(2+) sulfate (1:1) monohydrate CAS 10034-96-5
Anhydrous 151.00 CAS 7785-87-7
Manganese Sulfate contains not less than 98.0 percent and not more than 102.0 percent of MnSO4·H2O.
Identification: A solution (1 in 10) responds to the tests for Manganese 191 and for Sulfate.
Loss on ignition: Ignite it at 450 to constant weight: it loses between 10.0% and 13.0% of its weight.
Substances not precipitated by ammonium sulfide: Dissolve 2.0 g in 90 mL of water, add 5 mL of ammonium hydroxide, warm the solution, and pass hydrogen sulfide through the solution for about 30 minutes. Dilute with water to 100 mL, mix, and allow the precipitate to settle. Decant the supernatant through a filter, transfer 50 mL of the clear filtrate to a tarred dish, evaporate to dryness, and ignite, gently at first and finally at 800 ± 25 : the weight of the residue does not exceed 5 mg (0.5%).
Manganese Sulfate FCC Food Grade Specifications
MnSO4-H2O Formula weightt 169.02
CAS 7785-87-7
DESCRIPTION
Manganese Sulfate occurs as a pale-pink, granular powder. It is freely soluble in water, but is insoluble in alcohol.
Function: Nutrient.
REQUIREMENTS
Identification: A 1:10 aqueous solution gives positive tests for Manganese and for Sulfate.
Assay: Not less than 98.0% and not more than 102.0% of MnSO4·H2O.
Arsenic: Not more than 3 mg/kg.
Lead: Not more than 4 mg/kg.
Loss on Heating: Between 10.0% and 13.0%.
Selenium: Not more than 0.003%.
Manganese Sulfate Monohydrate Analytical Reagent Grade Specifications
Manganese Sulfate Specifications
Manganese Sulfate Monohydrate
Manganese (II) Sulfate Monohydrate
Manganous Sulfate Monohydrate
MnSO4-H2O
Formula Weight 169.02
CAS Number 10034-96-5
REQUIREMENTS
Assay: 98.0-101.0% MnSO4-H2O
Loss on ignition: 10.0-12.0%
Substances reducing permanganate: Passes test
MAXIMUM ALLOWABLE
Insoluble matter: 0.01%
Chloride (Cl): 0.005%
Calcium (Ca): 0.005%
Magnesium (Mg): 0.005%
Nickel (Ni): 0.02%
Potassium (K): 0.01%
Sodium (Na): 0.05%
Zinc (Zn): 0.005%
Heavy metals (as Pb): 0.002%
Iron (Fe): 0.002%.
The Uses of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous:
Manganese sulfate is used primarily as a fertilizer and as livestock supplement where soils are deficient in manganese. It is also used in some glazes, varnishes, ceramics, and fungicides. Manganese is used for prevention and treatment of manganese deficiency, a condition in which the body doesn't have enough manganese. It is also used for hay fever, osteoporosis, osteoarthritis, wound healing, and many other conditions. It has a role as a nutraceutical.
The MSDS-SDS Hazard Statement of Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous:
Manganese Sulfate or Manganese Sulphate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 14-Jan-23
Section 1. Product Information
Product Name & Other Names: Manganese Sulfate or Manganese Sulphate.
manganese sulfate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. The monohydrate is most common.
Synonym: Sulfuric Acid, Manganese salt monohydrate, Manganous Sulphate
Formula: MnSO4-H2O, MnSO4
CAS No.: 10034-96-5 (monohydrate) 7785-87-7 (anhydrous)
EINECS EC Number: 232-089-9
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335
Specific target organ toxicity - repeated exposure (Category 2), H373
Acute aquatic toxicity (Category 2), H401
Labelling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Aquatic Toxicity |
GHS Label Elements |
Signal Words: Warning
Hazard statements:
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H401: Toxic to aquatic life.
Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Section 3: Composition and Information on Ingredients
Product Name & Other Names: Manganese Sulfate monohydrate or Manganese Sulphate monohydrate.
Synonym: Sulfuric Acid, Manganese salt monohydrate, Manganous Sulphate
CAS No.: 10034-96-5; 98-100% by Weight.
EINECS EC Number: 232-089-9
Section 4. First Aid & Procedure
Always get medical attention after the first aid is over.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.
Section 5. Fire Fighting Measures
Flash Point: N/A
Extinguishing Medium: Water fog or other medium appropriate to surrounding fire conditions.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire. The use of fire extinguishers of the chlorinated hydrocarbon type is not recommended, as toxic products will probably be produced by the decomposition of the extinguishing medium when it encounters hot manganese compounds.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
Section 6. Spills and Disposals
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Pick up and arrange disposal without creating dust. Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.
Section 7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, aluminum, and magnesium.
Section 8. Exposure Controls & Personal Protection
Exposure Limits:.
OSHA PEL: 5mg/COM Ceiling for manganese compounds as Mn.
ACGIH TLV: 0.2 mg/CBM (TWA) for manganese, elemental and inorganic compounds as Mn.
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
Section 9. Physical & Chemical Data
Appearance: Solid. Slightly pink powder.
Odor: Odorless
Odor threshold: Not available.
pH Value: 4.0 - 7.0
Relative density: around 2.95
Melting Point: 2000C.
Boiling Point: 8500C.
Flash point: Not available.
Decomposition: 2000C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Easily soluble in water, insoluble in ethanol.
Viscosity: Not available.
Section 10. Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, aluminum and magnesium.
Conditions to Avoid: Incompatible materials, exposure to moist air or water, excessive heat.
Hazardous Decomposition Products: Carbon dioxide, sulfur oxides, oxides of manganese.
Hazardous Polymerization: Will not occur.
Section 11. Toxicological Information
Toxicity to Animals: LD50/LC50, N/A. Oral (Rat) 2150mg/kg. Does not belong to toxic substances.
Chronic Effects on Humans: Manganese sulfate or Manganese Sulphate is toxic to lungs, central nervous system (CNS), liver and kidney. Chronic manganese poisoning can result from excessive inhalation and ingestion exposure and involves impairment of the central nervous system. Early symptoms include sluggishness, sleepiness, and weakness in the legs. Advanced cases have shown fixed facial expression, emotional disturbances, spastic gait and falling. Illness closely resembles Parkinson's Disease. Kidney effects, blood changes and manganese psychosis also may occur because of long-term exposure. Chronic inhalation exposure can cause lung damage.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, SHA.
Mutagenic: Possible for humans. Laboratory experiments have shown mutagenic effects.
Reproductive Toxicity: May damage the reproductive system.
Teratogenic: Teratogenic effects shown in lab animals.
Section 12. Ecological Information
Toxicity to fish: No information available.
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 13. Disposal Suggestions
Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.
Section 14. Transport and Label Information
DOT USA: Not dangerous goods
IMDG/IMO:
UN number: 3077; Class: 9; Packing group: III; EMS-No: F-A, S-F
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Manganese Sulfate Monohydrate)
IATA/:
UN number: 3077; Class: 9; Packing group: III;
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Manganese Sulfate Monohydrate)
ADR/RID Europe:
UN number: 3077; Class: 9; Packing group: III;
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Manganese Sulfate Monohydrate)
Section 15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Section 16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Structure
CAS Number Monohydrate 10034-96-5 and Anhydrous 7785-87-7, Manganese Sulfate or Manganese Sulphate Monohydrate Anhydrous Manufacturer Exporter
ANMOL CHEMICALS & PHARMACEUTICALS Pvt. Ltd.
India, USA, Europe, UAE
TELEPHONE: +912223770100
Navi Mumbai, INDIA
e-mail: info(At the rate i.e. @)anmol.org
Copyright. 1-feb-23
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